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Reviews in Mineralogy and Geochemistry; January 2003; v. 52;1; p. 363-405; DOI: 10.2113/0520363
© 2003 Mineralogical Society of America
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Uranium-series Dating of Marine and Lacustrine Carbonates

R.L. Edwards1, C.D. Gallup2 and H. Cheng1

1 Department of Geology and Geophysics, University of Minnesota, Twin Cities, Minneapolis, Minnesota, 55455, U.S.A.
2 Department of Geological Sciences, University of Minnesota, Duluth Duluth, Minnesota, 55812, U.S.A.

The first 20% of the full text of this article appears below.


    1. HISTORICAL CONSIDERATIONS
 
Of the possible uranium-series dating schemes, the most important and most widely applied to marine carbonates is 230Th dating, with 231Pa dating playing an increasingly important role. For this reason, this review will focus on these two methods. 230Th dating, also referred to as U/Th dating or 238U-234U-230Th dating, involves calculating ages from radioactive decay and ingrowth relationships among 238U, 234U, and 230Th. 232Th is also typically measured as a long-lived, essentially stable index isotope (over the time scales relevant to 230Th dating). At present 230Th dating can, in principle, be used to date materials as young as 3 years and in excess of 600,000 years (Edwards et al. 1987a, 1993; Edwards 1988; see Stirling et al. 2001 for an example of dating corals in excess of 600,000 years old). 231Pa dating, also referred to as U/Pa dating, involves calculating ages from the ingrowth of 231Pa from its grandparent 235U. At present 231Pa dating can be used to date materials as young as 10 years and as old 250,000 years (Edwards et al. 1997). 230Th dating covers all of the 231Pa time range and more, with somewhat higher precision, and is therefore the method of choice if a single method is applied. However, the combination of 231Pa and 230Th dating is of great importance in assessing possible diagenetic mobilization of the pertinent nuclides, and thereby, the accuracy of the ages (Allegre 1964; Ku 1968). Even if the primary age exceeds the 250,000 year limit of 231Pa dating, the combined methods can be used to assess the degree to which the samples have remained closed over the past 250,000 years (e.g., Edwards et al. 1997). Thus 231Pa analysis can play an important role in assessing age accuracy. Taken together, 230Th and 231. . . [Full Text of this Article]




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