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Reviews in Mineralogy and Geochemistry; January 2006; v. 62;1; p. 231-241; DOI: 10.2138/rmg.2006.62.10
© 2006 Mineralogical Society of America
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The Partitioning of Water Between Nominally Anhydrous Minerals and Silicate Melts

Simon C. Kohn and Kevin J. Grant1

Department of Earth Sciences, University of Bristol Bristol, BS8 1RJ, United Kingdom, e-mail: Simon.Kohn@bristol.ac.uk

The first 20% of the full text of this article appears below.


    INTRODUCTION
 
Many chapters in this volume emphasize that water plays a crucial role in determining the properties and behavior of the mantle. One of the most important examples of the effect of water on mantle behavior is its dramatic effect in reducing melting temperatures, and, in the case of decompression melting, increasing the depth of initiation of melting. Even the small amount of water which could be contained within nominally anhydrous minerals (NAMs) is sufficient to play an important role in generation of MORBs (Hirth and Kohlstedt 1996; Asimow and Langmuir 2003; Asimow et al. 2004). Figure 1Go illustrates how, according to the model of Aubaud et al. (2004), small amounts of water affect the depth of initiation of melting in upwelling mantle. Furthermore, in regions of the mantle where large concentrations of water could be stored (e.g., the transition zone), phase changes could release water and generate melt in previously unexpected environments (Bercovici and Karato 2003; Hirschmann 2006). The effect of water on mantle melting is one of many reasons why knowledge of the spatial and temporal distribution of water in the mantle is crucial to understanding the evolution of our planet.


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Figure 1. Model for the effect of small concentrations of water in the mantle on the depth of initiation of mantle melting (after Aubaud et al. 2004). Note that even 200 ppm water reduces the depth of melting by at least 20 km and that the effect is more pronounced for a high mantle potential temperature.

 
It is also possible to look at this problem from the other direction, because the products of partial melting of the mantle provide an opportunity to assess the water concentrations in the source regions of these melts. The amount of water in different regions of . . . [Full Text of this Article]







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