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Institute for Applied Geosciences, Technical University of Berlin, D-13355 Berlin, Germany, Department 4, Chemistry of the Earth, GeoForschungsZentrum Potsdam, Telegrafenberg, D-14473 Potsdam, Germany, axel.liebscher@tu-berlin.de
Isotope Geochemistry and Mineral Resources, Departement Erdwissenschaften NO, ETH Zentrum, CH-8092 Zurich, Switzerland, christoph.heinrich@erdw.ethz.ch
| The first 20% of the full text of this article appears below. |
| INTRODUCTION |
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Different sources of fluids and variable paths of recycling volatile components from the hydrosphere and atmosphere through the solid interior of the Earth lead to a broad range of fluid compositions, from aqueous liquids and gases through water-rich silicate or salt melts to carbon-rich endmember compositions. Different rock regimes in the crust and mantle generate characteristic ranges of fluid composition, which depending on pressure, temperature and composition are miscible to greatly variable degrees. For example, aqueous liquids and vapors are increasingly miscible at elevated pressure and temperature. The degree of this miscibility is, however, greatly influenced by the presence of additional carbonic or salt components. A wide range of fluid–fluid interactions results from this partial miscibility of crustal fluids. Vastly different chemical and physical properties of variably miscible fluids, combined with fluid flow from one pressure – temperature regime to another, therefore have major consequences for the chemical and physical evolution of the crust and mantle.
Several recent textbooks (e.g., Walther and Wood 1986; Carrol and Holloway 1994; Shmulovich et al. 1995;
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