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Paleoelevation Reconstruction using Pedogenic Carbonates

Department of Geosciences, University of Arizona, Tucson, Arizona, 85721, U.S.A., quadej@email.arizona.edu

Carmala Garzione

Department of Earth and Environmental Sciences, University of Rochester, Rochester, New York, 14627, U.S.A., garzione@earth.rochester.edu

John Eiler

Division of Geological and Planetary Sciences, California Institute of Technology, Pasadena, California, 91125, U.S.A., eiler@gps.caltech.edu

The first 20% of the full text of this article appears below.

Paleoelevation reconstruction using stable isotopes, although a relatively new science, is making a significant contribution to our understanding of the recent growth of the world’s major orogens. In this review we examine the use of both light stable isotopes of oxygen and the new "clumped-isotope" (₄₇) carbonate thermometer in carbonates from soils. Globally, the oxygen isotopic composition (¹⁸O) of rainfall decreases on average by about 2.8 /km of elevation gain. This effect of elevation will in turn be archived in the ¹⁸O value of soil carbonates, and paleoelevation can be reconstructed, provided (1) temperature of formation can be estimated, (2) the effects of evaporation are small, (3) the effects of climate change can be accounted for, and (4) the isotopic composition of the carbonate is not diagenetically altered. We review data from modern soils to evaluate some of these issues and find that evaporation commonly elevates ¹⁸O values of carbonates in deserts, an effect that would lead to underestimates of paleoelevation. Some assessment of paleoaridity, using qualitative indicators or carbon isotopes from soil carbonate, is therefore useful in evaluating the oxygen isotope-based estimates of paleoelevation. Sampling from deep (> 50 cm) in paleosols helps reduce the uncertainties arising from seasonal temperature fluctuations and from evaporation.

The new "clumped-isotope" (₄₇) carbonate thermometer, expressed as ₄₇, offers an independent and potentially very powerful approach to paleoelevation reconstruction. In contrast to the use of ¹⁸O values, nothing need be known about the isotopic composition of water from which carbonate grew in order to estimate of temperature of carbonate formation from ₄₇ values. Using assumed temperature lapse rates with elevation, paleoelevations can thereby be reconstructed.

Case studies from the Andes and Tibet show how these methods can be used alone or in combination to estimate paleoelevation. In both cases, the potential for . . . [Full Text of this Article]

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